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Kapcsolat
Asymmetric Hydroformylation of 4-Vinyl-1,3-dioxolan-2-one |
Tartalom: | http://real.mtak.hu/48616/ |
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Archívum: | MTA Könyvtár |
Gyűjtemény: |
Status = In Press
Type = Article |
Cím: |
Asymmetric Hydroformylation of 4-Vinyl-1,3-dioxolan-2-one
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Létrehozó: |
Pongrácz, Péter
Kollár, László
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Kiadó: |
Wiley
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Dátum: |
2016
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Téma: |
QD Chemistry / kémia
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Tartalmi leírás: |
A chiral cyclic carbonate, 4-vinyl-1,3-dioxolan-2-one was used as racemic substrate in asymmetric
hydroformylation. The catalysts were formed in situ from “pre-formed” PtCl2(diphosphine) and tin(II) chloride. (2S,4S)-2,4-Bis(diphenylphosphinopentane ((S,S)-BDPP)), (S,S)-2,3-O-izopropylidine-2,3-dihydroxy-1,4-bis (diphenylphosphino)butane ((S,S)-DIOP)), and (R)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ((R)-BINAP)) were used as optically active diphosphine ligands. The platinum-containing catalytic systems provided surprisingly high activity. The hydroformylation selectivities of up to 97% were accompanied by perfect regioselectivity towards the dioxolane-based linear aldehyde. The enantiomeric composition of all components in the reaction mixture was determined and followed throughout the reaction. The unreacted 4-vinyl-1,3-dioxolan-2-one was recovered in optically active form. The kinetic resolution was rationalized using the enantiomeric composition of the substrate and the products. |
Nyelv: |
magyar
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Típus: |
Article
PeerReviewed
info:eu-repo/semantics/article
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Formátum: |
text
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Azonosító: |
Pongrácz, Péter and Kollár, László (2016) Asymmetric Hydroformylation of 4-Vinyl-1,3-dioxolan-2-one. Journal of Heterocyclic Chemistry. ISSN 0022-152X, ESSN: 1943-5193 (In Press)
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Kapcsolat: |