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Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions

  • Metaadatok
Tartalom: http://real.mtak.hu/41742/
Archívum: MTA Könyvtár
Gyűjtemény: Status = In Press

Type = Article
Cím:
Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions
Létrehozó:
Marosvölgyi-Haskó, Diána
Kollár, László
Lengyel, Blanka
Tukacs, JĂłzsef M.
Mika, László Tamás
Kiadó:
Wiley
Dátum:
2015
Téma:
QD04 Organic chemistry / szerves kémia
Tartalmi leírás:
g-Valerolactone (GVL) was proposed as a renewable, nontoxicreaction medium with negligible vapor pressure for homoge-neous Pd-catalyzed aminocarbonylation reactions. Iodoben-zene as a model substrate and its 4-substituted derivativeswere converted to the corresponding 2-ketocarboxamides withhigh conversions and chemoselect ivities in g-valerolactone.The effect of carbon monoxide pressure and reaction tempera-ture on the conversion and selectivities were studied in therange 1–50 bar and 25–1008C, respectively. The highest con-version and selectivity was achieved at 25 bar and 50 8C for io-dobenzene in GVL for 24 h.
Nyelv:
angol
Típus:
Article
PeerReviewed
info:eu-repo/semantics/article
Formátum:
text
Azonosító:
Marosvölgyi-Haskó, Diána and Kollár, László and Lengyel, Blanka and Tukacs, József M. and Mika, László Tamás (2015) Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions. ChemPlusChem, 87. pp. 1-7. ISSN 2192-6506 (In Press)
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