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Kapcsolat
Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions |
Tartalom: | http://real.mtak.hu/41742/ |
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Archívum: | MTA Könyvtár |
Gyűjtemény: |
Status = In Press
Type = Article |
Cím: |
Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions
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Létrehozó: |
Marosvölgyi-Haskó, Diána
Kollár, László
Lengyel, Blanka
Tukacs, JĂłzsef M.
Mika, László Tamás
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Kiadó: |
Wiley
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Dátum: |
2015
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Téma: |
QD04 Organic chemistry / szerves kémia
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Tartalmi leírás: |
g-Valerolactone (GVL) was proposed as a renewable, nontoxicreaction medium with negligible vapor pressure for homoge-neous Pd-catalyzed aminocarbonylation reactions. Iodoben-zene as a model substrate and its 4-substituted derivativeswere converted to the corresponding 2-ketocarboxamides withhigh conversions and chemoselect ivities in g-valerolactone.The effect of carbon monoxide pressure and reaction tempera-ture on the conversion and selectivities were studied in therange 1–50 bar and 25–1008C, respectively. The highest con-version and selectivity was achieved at 25 bar and 50 8C for io-dobenzene in GVL for 24 h.
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Nyelv: |
angol
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Típus: |
Article
PeerReviewed
info:eu-repo/semantics/article
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Formátum: |
text
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Azonosító: |
Marosvölgyi-Haskó, Diána and Kollár, László and Lengyel, Blanka and Tukacs, József M. and Mika, László Tamás (2015) Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions. ChemPlusChem, 87. pp. 1-7. ISSN 2192-6506 (In Press)
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Kapcsolat: |