| Tartalom: |
http://real.mtak.hu/41742/ |
| Archívum: |
MTA Könyvtár |
| Gyűjtemény: |
Status = In Press
Type = Article
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| Cím: |
Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions
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| Létrehozó: |
Marosvölgyi-Haskó, Diána
Kollár, László
Lengyel, Blanka
Tukacs, JĂłzsef M.
Mika, László Tamás
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| Kiadó: |
Wiley
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| Dátum: |
2015
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| Téma: |
QD04 Organic chemistry / szerves kémia
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| Tartalmi leírás: |
g-Valerolactone (GVL) was proposed as a renewable, nontoxicreaction medium with negligible vapor pressure for homoge-neous Pd-catalyzed aminocarbonylation reactions. Iodoben-zene as a model substrate and its 4-substituted derivativeswere converted to the corresponding 2-ketocarboxamides withhigh conversions and chemoselect ivities in g-valerolactone.The effect of carbon monoxide pressure and reaction tempera-ture on the conversion and selectivities were studied in therange 1–50 bar and 25–1008C, respectively. The highest con-version and selectivity was achieved at 25 bar and 50 8C for io-dobenzene in GVL for 24 h.
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| Nyelv: |
angol
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| Típus: |
Article
PeerReviewed
info:eu-repo/semantics/article
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| Formátum: |
text
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| Azonosító: |
Marosvölgyi-Haskó, Diána and Kollár, László and Lengyel, Blanka and Tukacs, József M. and Mika, László Tamás (2015) Application of g-Valerolactone as an Alternative Biomass-Based Medium for Aminocarbonylation Reactions. ChemPlusChem, 87. pp. 1-7. ISSN 2192-6506 (In Press)
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