| Tartalom: |
http://www.sciencedirect.com/science/article/pii/S0020169... |
| Archívum: |
MTA Könyvtár |
| Gyűjtemény: |
Status = Published
Type = Article
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| Cím: |
Cationic copper(I) and silver(I) nitrile complexes with fluorinated weakly coordinating anions: Metal-nitrile bond strength and its influence on the catalytic performance
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| Létrehozó: |
Zhang, Y. M.
Sun, W.
Freund, C.
Santos, A. M.
Mink, János
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| Dátum: |
2006
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| Téma: |
QD Chemistry / kémia
QD03 Inorganic chemistry / szervetlen kémia
TK Electrical engineering. Electronics Nuclear engineering / elektrotechnika, elektronika, atomtechnika
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| Tartalmi leírás: |
Copper(I) and silver(I) complexes of formulae [Cu(NCCH3)(4)](+)[A](-) ([A](-) = [B(C6F5)(4)](-) (1), (B[C6H3(CF3)(2)](4))(-) (2), [(C6F5)(3)B-C3H3N2-B(C6F5)(3)](-) (3), and [Ag(NCCH3)(4)](+)[B(C6F5)(4)](-) (4) are examined with particular emphasis on the strength of their M-N bond and its influence on the catalytic performance of these complexes in cyclopropanation and aziridination. To examine the strength of the M-N interactions, vibrational spectra of the related hydrogenated and deuterated species [Cu(NCCH3)(4)](+), [Cu(NCCD3)(4)](+), [Ag(NCCH3)(4)](+), and [Ag(NCCD3)(4)](+) are also determined. It is found that the metal-nitrile bond strength is an important factor for the catalytic activity of the respective complexes.
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| Típus: |
Article
PeerReviewed
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| Formátum: |
text
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| Azonosító: |
Zhang, Y. M. and Sun, W. and Freund, C. and Santos, A. M. and Mink, János (2006) Cationic copper(I) and silver(I) nitrile complexes with fluorinated weakly coordinating anions: Metal-nitrile bond strength and its influence on the catalytic performance. INORGANICA CHIMICA ACTA, 359 (15). pp. 4723-4729. ISSN 0020-1693
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