| Tartalom: |
http://pubs.acs.org/doi/abs/10.1021/ic800745g |
| Archívum: |
MTA Könyvtár |
| Gyűjtemény: |
Status = Published
Type = Article
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| Cím: |
Oxidative C-H and C-C bond cleavage by a (2,2'-bipyridine)copper(I) chloride complex
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| Létrehozó: |
Csonka, Róbert
Kaizer, József
Giorgi, Michel
Hajba, László
Mink, János
Speier, Gábor
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| Dátum: |
2008
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| Téma: |
QD Chemistry / kémia
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| Tartalmi leírás: |
Acetonitrile is easily oxygenated at ambient reaction conditions to copper(II) oxalate [Cu(bpy)(ox)] n mediated by copper(I) chloride in the presence of 3,5-di-tert-butylcatechol and 2,2'-bipyridine. In the case of other nitriles (e.g., propionitrile), instead, the unusual and selective 1,4-extradiol cleavage of 3,5-di-tert-butylcatechol occurs to give copper(II) tert-butylmaleate [Cu(bma)(bpy)(H2O)]n in good yield.
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| Típus: |
Article
PeerReviewed
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| Formátum: |
text
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| Azonosító: |
Csonka, Róbert and Kaizer, József and Giorgi, Michel and Hajba, László and Mink, János and Speier, Gábor (2008) Oxidative C-H and C-C bond cleavage by a (2,2'-bipyridine)copper(I) chloride complex. INORGANIC CHEMISTRY, 47 (14). pp. 6121-6123. ISSN 0020-1669
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