| Tartalom: |
http://real.mtak.hu/6342/ |
| Archívum: |
MTA Könyvtár |
| Gyűjtemény: |
Status = Published
Type = Article
|
| Cím: |
4-Sulfonatocalix[6]arene-induced aggregation of ionic liquids
|
| Létrehozó: |
Wintgens, Veronique
Le Coeur, Clémence
Amiela, Catherine
Guigner, Jean-Michel
Harangozó, József G.
Miskolczy, Zsombor
Biczók, László
|
| Kiadó: |
American Chemical Society
|
| Dátum: |
2013
|
| Téma: |
QD Chemistry / kémia
|
| Tartalmi leírás: |
The interaction of 4-sulfonatocalix[6]arene (SCX6) macrocycle with 1-alkyl-3-methylimidazolium type of ionic liquids possessing dodecyl, tetradecyl, or hexadecyl substituent was studied in aqueous solution at 298 K. Host-guest complexation promoted the spontaneous self-assembly into nanoparticles of 7:1 ionic liquid:SCX6 stoichiometry. Positively charged and stable nanoparticles were produced in solutions of 7-200-fold excess of ionic liquid as compared to the amount of SCX6. The negatively charged nanoparticles formed in solutions having 2-7 ionic liquid:SCX6 molar ratios evolved into larger species. The stability of the nanoparticles increased with the lengthening of aliphatic chain of the ionic liquid. Cryo-TEM experiments showed dense particles generally with spherical shape and multilayered structure, which has been confirmed by small-angle neutron scattering. © 2013 American Chemical Society.
|
| Típus: |
Article
PeerReviewed
|
| Formátum: |
text
|
| Azonosító: |
Wintgens, Veronique and Le Coeur, Clémence and Amiela, Catherine and Guigner, Jean-Michel and Harangozó, József G. and Miskolczy, Zsombor and Biczók, László (2013) 4-Sulfonatocalix[6]arene-induced aggregation of ionic liquids. LANGMUIR, 29 (25). pp. 7682-7688. ISSN 0743-7463
|
| Kapcsolat: |
|
