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The Fulleride Polymer Mg5C60

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Tartalom: http://real.mtak.hu/6112/
Archívum: MTA Könyvtár
Gyűjtemény: Status = Published


Type = Article
Cím:
The Fulleride Polymer Mg5C60
Létrehozó:
Quintavalle, Dario
Simon, Ferenc
Jánossy, András
Borondics, F.
Baserga, A.
Kamarás, Katalin
Pekker, Sándor
Kiadó:
Wiley - VCH Verlag
Dátum:
2007
Téma:
QC Physics / fizika
QC06 Physics of condensed matter / szilárdtestfizika
Tartalmi leírás:
We synthesized a series of MgxC60 samples with nominal
composition of x between 1 and 6 via solid state reaction
between C 60 and Mg powder. For x = 5 a two dimensional
structure was found. The polymer phase is unusually stable up to
high temperatures, it remains unchanged at 823 K for 20 minutes
as confirmed by ESR. The mid-infrared absorption spectrum
suggests that the polymer sheets contain single bonded fulleride
ions. Both the spin susceptibility and microwave conductivity
measurements show that Mg5C60 is metallic for T > 200 K. The
transition from metallic to insulating states around 200 K may
be attributed to Anderson localization. © 2007 WILEY-VCH Verlag
GmbH & Co. KGaA.
Típus:
Article
PeerReviewed
Formátum:
text
Azonosító:
Quintavalle, Dario and Simon, Ferenc and Jánossy, András and Borondics, F. and Baserga, A. and Kamarás, Katalin and Pekker, Sándor (2007) The Fulleride Polymer Mg5C60. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 244. pp. 3853-3856. ISSN 0370-1972
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