Vibrational Spectroscopic Study of SiO2-based Nanotubes
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Tartalom: http://real.mtak.hu/6000/
Archívum: MTA Könyvtár
Gyűjtemény: Status = Published


Type = Article
Cím:
Vibrational Spectroscopic Study of SiO2-based Nanotubes
Létrehozó:
Fischer, Christian E.
Mink, János
Hajba, László
Bacsik, Zoltán
Németh, Csaba
Mihály, Judith
Raitha, Alexander
Cokoja, Mirza
Kühna, Fritz E.
Kiadó:
Elsevier
Dátum:
2013
Téma:
QD Chemistry / kémia
RM Therapeutics. Pharmacology / terápia, gyógyszertan
Tartalmi leírás:
Novel organic-inorganic hybrid nanotubes containing silica and ethane (EtSNT), ethylene (ESNT) and acetylene (ASNT) units, as well as brominated ESNT (Br-ESNT) and glycine-modified Br-ESNT (Gly-ESNT) have been studied by IR and Raman spectroscopy. The results are compared with the spectral features for conventional silica nanotubes (SNT) and amorphous silica. Bands peculiar to organic moieties have been detected and assigned. Assignment of the silicate backbone vibrations was based on the results of normal coordinate calculations. Furthermore, characteristic silicate, so-called ?nanotube? vibrations have been identified and their band positions have been summarized to serve as a future reference for such compounds. SiOSi antisymmetric stretchings were observed in the range 1000-1110 cm-1, while the symmetric stretchings appeared between 760-960 cm-1 for EtSNT, ESNT and Br-ESNT.
Force constants have been refined for models of the repeating structure units: O3SiOSi(OSi)3 for SNT and SiCHnCHnSi(OSi)3 for organosilica nanotubes (n = 2, EtSNT; n = 1, ESNT and n = 0, ASNT). The calculated SiO stretching force constants were increased from 4.79 to 4.88 and 5.11 Ncm-1 for EtSNT, ESNT and ASNT, respectively. The force constants have been compared with those for several silicates and SiO bond length are predicted and discussed.
Típus:
Article
PeerReviewed
Formátum:
text
Azonosító:
Fischer, Christian E. and Mink, János and Hajba, László and Bacsik, Zoltán and Németh, Csaba and Mihály, Judith and Raitha, Alexander and Cokoja, Mirza and Kühna, Fritz E. (2013) Vibrational Spectroscopic Study of SiO2-based Nanotubes. VIBRATIONAL SPECTROSCOPY, 66. pp. 104-118. ISSN 0924-2031
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